Geochemical detection of carbon dioxide in dilute aquifers
© Carroll et al; licensee BioMed Central Ltd. 2009
Received: 01 October 2008
Accepted: 26 March 2009
Published: 26 March 2009
Carbon storage in deep saline reservoirs has the potential to lower the amount of CO2 emitted to the atmosphere and to mitigate global warming. Leakage back to the atmosphere through abandoned wells and along faults would reduce the efficiency of carbon storage, possibly leading to health and ecological hazards at the ground surface, and possibly impacting water quality of near-surface dilute aquifers. We use static equilibrium and reactive transport simulations to test the hypothesis that perturbations in water chemistry associated with a CO2 gas leak into dilute groundwater are important measures for the potential release of CO2 to the atmosphere. Simulation parameters are constrained by groundwater chemistry, flow, and lithology from the High Plains aquifer. The High Plains aquifer is used to represent a typical sedimentary aquifer overlying a deep CO2 storage reservoir. Specifically, we address the relationships between CO2 flux, groundwater flow, detection time and distance. The CO2 flux ranges from 103 to 2 × 106 t/yr (0.63 to 1250 t/m2/yr) to assess chemical perturbations resulting from relatively small leaks that may compromise long-term storage, water quality, and surface ecology, and larger leaks characteristic of short-term well failure.
For the scenarios we studied, our simulations show pH and carbonate chemistry are good indicators for leakage of stored CO2 into an overlying aquifer because elevated CO2 yields a more acid pH than the ambient groundwater. CO2 leakage into a dilute groundwater creates a slightly acid plume that can be detected at some distance from the leak source due to groundwater flow and CO2 buoyancy. pH breakthrough curves demonstrate that CO2 leaks can be easily detected for CO2 flux ≥ 104 t/yr within a 15-month time period at a monitoring well screened within a permeable layer 500 m downstream from the vertical gas trace. At lower flux rates, the CO2 dissolves in the aqueous phase in the lower most permeable unit and does not reach the monitoring well. Sustained pumping in a developed aquifer mixes the CO2-affected water with the ambient water and enhances pH signal for small leaks (103 t/yr) and reduces pH signal for larger leaks (≥ 104t/yr).
The ability to detect CO2 leakage from a storage reservoir to overlying dilute groundwater is dependent on CO2 solubility, leak flux, CO2 buoyancy, and groundwater flow. Our simulations show that the most likely places to detect CO2 are at the base of the confining layer near the water table where CO2 gas accumulates and is transported laterally in all directions, and downstream of the vertical gas trace where groundwater flow is great enough to transport dissolved CO2 laterally. Our simulations show that CO2 may not rise high enough in the aquifer to be detected because aqueous solubility and lateral groundwater transport within the lower aquifer unit exceeds gas pressure build-up and buoyancy needed to drive the CO2 gas upwards.
Carbon storage as a liquid, gas, dissolved carbon, or as carbonate minerals has the potential to significantly offset global warming caused by anthropogenic combustion of fossil fuels [1, 2]. It is generally accepted that the most suitable systems for geologic storage are depleted oil and deep saline reservoirs, because they are not viable for domestic, industrial, and agricultural uses and they are separated from the atmosphere by 1000s of meters of geologic strata. Despite the physical separation between a storage reservoir and a useable aquifer, there is still concern that storage reservoirs may leak through abandoned wells or along faults and be released back to the atmosphere. Leakage of supercritical CO2 at depth will change to its gas state at lower pressures associated with shallow aquifers, and may be accompanied with deeper formation water. Leakage would reduce the efficacy of carbon storage, possibly leading to health and ecological hazards at the ground surface, and possibly negatively impacting water quality of near-surface dilute aquifers [3–8]. In order to assess risk and long-term liability it is important to utilize sensitive monitoring techniques that both detect leaks and quantify the magnitude of the leak .
Carbon dioxide leakage rates that may compromise storage effectiveness and safety can range over several orders of magnitude. We have chosen to use units of metric tons per year (t/y) to directly compare leakage rates with the amount of CO2 that may be injected from a large coal plant. At the lower end of the scale, a detectable anthropogenic CO2 flux from the subsurface must be greater than about 102 t/yr to exceed CO2 produced by biological mineralization of organic matter [9–12]. Anthropogenic CO2 fluxes of 103 to 105 t/yr are above background and represent small leaks corresponding to only 0.01% to 1% of the annual amount of CO2 injected to the subsurface for a gigawatt coal plant that generates and sequesters 107 t/yr of CO2. Although these leakage rates are small relative to the amount of CO2 that can be stored in deep reservoirs, they are comparable with CO2 fluxes from abandoned wells to natural CO2 reservoirs and volcanic activity [7, 13, 14]. Slow leakage of CO2 gas from small leaks can present a hazard if it builds up in enclosed areas like the basements of buildings or holes in the earth. This would include fault leaks and slow well leaks, and has been the cause of ecological hazards and of human fatalities in areas with volcanic emissions of carbon dioxide [15, 16]. Higher carbon dioxide release rates on the order of 20% of the annual amount of injected CO2 are equivalent to the largest reported amount of CO2 released from catastrophic well failure that was mitigated within seven days . Water chemistry associated with CO2 gas leakage into domestic groundwater resources maybe an important way to monitor the potential for further leakage to the surface over a wide range of fluxes, because the acidity associated with dissolved CO2 will alter the ambient water chemistry.
In this paper we use static equilibrium and reactive transport simulations to test the hypothesis that perturbations in water chemistry associated with a CO2 gas leak into dilute groundwater are important measures for the potential release of CO2 to the atmosphere. Simulation parameters are constrained by groundwater chemistry, flow, and lithology from the High Plains aquifer. The High Plains aquifer is used to represent a typical sedimentary aquifer that may overly a deep CO2 storage reservoir. Specifically, we address the relationships between CO2 flux (103 to 2 × 106 t/yr), detection time and detection distance.
Static Equilibrium Model
In this section we establish that increases in pCO2 perturb groundwater chemistry of domestic aquifers by comparing the geochemical signatures of the High Plains aquifer and a model aquifer column saturated with CO2(g) as a function of depth. This geochemical model is incorporated into the reactive transport calculations that describe the ability for detection of stored CO2 that has leaked into a domestic aquifer.
Thermodynamic equilibrium constants from the Geochemists Workbench, thermo.dat database used to account for aqueous speciation .
Mass balance reactions
CaCO3 (Calcite) + H+ = Ca2+ + HCO3-
SiO2 (Quartz) = SiO2 (aq)
CO2(g) + H2O = H+ +HCO3-
CO2(aq) + H2O = H+ + HCO3-
CO32- + H+ = HCO3-
NaHCO3 + = Na++HCO3-
H2O = H+ + OH-
Geochemical response of CO2leak
The carbonate signature of the High Plains aquifer is distinct from a model sandstone aquifer exposed to CO2 gas that might leak from a much deeper storage reservoir. Figure 1 plots the pH, alkalinity as HCO3-, pCO2, total dissolved carbon concentrations, carbonate speciation, and the amount of calcite dissolved as a function of depth for the aquifer system equilibrated with pCO2 equal to the hydrostatic pressure. Equilibration of CO2 gas that might leak from a carbon sequestration aquifer would alter the ambient chemistry indicated here by the High Plains aquifer. As the CO2 gas leaks into the aquifer, it dissolves into the solution and drives the pH more acid and promotes some calcite dissolution according to the following mass balance reactions:
CO2(g) = CO2(aq) (1)
CO2(aq) + H2O = HCO3- + H+ (2)
CaCO3(calcite) + H+ = Ca2+ + HCO3- (3)
The chemical response of the aquifer to the leak increases with depth because higher hydrostatic pressures allow for higher pCO2. Thus solution pH decreases from pH 7.6 to pH 5.2, alkalinity as HCO3- increases from 10-2.6 to 10-1.3 molal, total dissolved carbon increases from 10-2.6 to 1 molal, and the pCO2 increases from 10-2.5 to 101.3 atm from the water table to 240 m below the surface in this calculation. It is clear from the comparison of the measured High Plains aquifer chemistry and the calculated aquifer water chemistry, that pH is a robust indicator of an influx of CO2 into a dilute aquifer from a much deeper carbon sequestration reservoir. There is a shift of about 2 pH units between the measured values in the High Plains aquifer and those in the leak simulation at depths 60 m below the water table. Although calculated HCO3- values fall within the range measured in the High Plains aquifers, alkalinity is equally important parameter to measure because when combined with pH it can be used to calculate the pCO2 (sum equations 1 and 2):
CO2(g) + H2O = HCO3- + H+ (4)
to confirm that the acidity is due to an influx of CO2 and to estimate the magnitude of the leak when measured over time and area. Note that in dilute-aquifers we assume that the dominant component to alkalinity is HCO3- concentration. This may not be the case in groundwater with significant concentrations of organic acids or sulfides.
The reason the calculated HCO3- concentrations fall within the range of those measured in the High Plains aquifer is that only minor amounts of calcite dissolve in response to the acidity generated by the CO2 leak. About 1% of the calcite dissolved in the deeper portion of the aquifer where pCO2 is higher, pH is more acid and CO2(aq) is the dominant carbonate species (Figure 1e, f). This suggests that calcite will effectively buffer acidity associated with a carbon dioxide leak in sandstone aquifers with minor amounts of calcite as well as in limestone and dolomite aquifers with major amounts of carbonate minerals.
Reactive Transport Model
In this section we explore the effects of CO2 flux, monitoring well location, pumping rate, and gravity-driven groundwater flow on leak detection using 3-D reactive transport simulations. We assume CO2 gas reaches the aquifer through an abandoned well or along a fault and is then transported in gas and fluid phases through the sedimentary layers. We use pH as the key geochemical indicator of carbon dioxide transport in the dilute aquifer. Simulation results are shown as pH breakthrough curves, contour plots at discrete time steps to capture transport details between the leak and monitoring well, and selected full-scale simulations shown as movies in additional files.
The numerical simulations were performed using a parallel-version of the Nonisothermal Unsaturated-Saturated Flow and Transport code (NUFT) to handle large 3-D reactive flow and transport calculations . The NUFT code is a highly flexible software package for modeling multiphase, multi-component heat and mass flow and reactive transport in unsaturated and saturated porous media. An integrated finite-difference spatial discretization scheme is used to solve mass and energy balance equations in both flow and reactive transport models. The resulting nonlinear equations are solved by the Newton-Raphson method. The NUFT code is capable of running on PCs, workstations, and major parallel processing platforms. Some of the application areas include: nuclear waste disposal, CO2 sequestration, groundwater remediation, and subsurface hydrocarbon production [23–26].
Hydrologic properties and parameters used for reactive transport simulations
10-17 – 2.5 × 10-10
30 – 55
Gas residual saturation (Sgr)
Irreducible water saturation (Slr)
van Genuchten parameter m
van Genuchten parameter α (Pa-1)
6.6 × 10-4
CO2 leakage flux (t/yr)
103, 104, 105, and 2 × 106 (0.63 to 1250 t/m2/yr)
Source Leak (m2)
40 × 40
Average groundwater flow (m/d)
Distance of the well from the leak (m)
0, 100, 200, 500
Well pumping rate (L/min)
0, 379, 757, 1893
The effect of groundwater pumping in developed aquifers on CO2 transport and detection is simulated by placing wells (equivalent diameter ~0.56 m) that are screened at about 110 m in the permeable zone above the CO2 leak source or at 100, 200, and 500 m downstream from the leak source. Pumping rates range from 0 to 1893 L/min to represent both undeveloped and developed aquifer regions. Typical irrigation rates for the High Plains aquifer vary from 379 to 1893 L/min (100 to 500 g/min) [27, 28].
Overview of CO2transport
The spatial and temporal development of a CO2 plume is the result of several concurrent processes: CO2 solubility, leak flux, CO2 buoyancy, and groundwater flow, where groundwater flow depends on the hydraulic gradient, permeability, porosity, and gas saturation. Aqueous solubility transfers CO2 from the gas phase to the groundwater and is in equilibrium with the pCO2 and carbonate mineralogy. Gas pressure and its inherent buoyancy relative to water transport CO2 gas vertically once the gas pressure exceeds the hydrostatic pressure until the gas reaches impermeable lithologies such as the clay layers near the water table in the High Plains aquifer. Gas pressure creates a vertical trace from the leak source to the top of the aquifer, where CO2 gas saturation builds up and is transported laterally along the base of the impermeable lithology. Groundwater flow moves the CO2-rich groundwater down gradient from the gas trace. Groundwater pumping for domestic, agricultural, or industrial uses tends to mix the CO2-affected waters with the ambient groundwater (see Developed Aquifers).
In our simulations, lateral dispersion at the top of the aquifer and within the highly permeable layers persists over time, because heterogeneity reflecting fingering and lateral discontinuities common in sedimentary formations was not incorporated into the geologic model. It is likely that a pH plume would be more complex when CO2 is diverted by less permeable regions due to lateral heterogeneity present in actual aquifer lithology. We did not include lateral heterogeneity in the geologic model because it could not be represented with the available data on the scale of our simulations.
Implications for Measurement, Monitoring, and Verification (MMV) Plans
Carbon dioxide leaking from a deep storage reservoir is likely to intercept groundwater resources before breeching the surface and reaching the atmosphere. The ubiquity of water wells may provide a simple means to test for such leakage before it reaches the surface. Occasional chemical testing for pH and alkalinity in water wells would indicate if carbon dioxide were entering the groundwater and if it is in danger of reaching the surface nearby. Much of the appeal of using pH and carbonate chemistry to detect CO2 leakage is that the chemical and hydrological processes governing detection are well understood and that it uses readily available technology. Groundwater pH and carbonate chemistry are good indicators for leakage of stored carbon into an overlying aquifer because elevated CO2 yields a more acid pH than the ambient groundwater. pH and alkalinity are good first level monitoring tools because these parameters capture the carbonate geochemistry associated with excess carbon dioxide in a dilute aquifer. It is important that pH and alkalinity be measured in the field, because their values will change as CO2-rich waters degas and carbonate minerals precipitate [32, 33]. A successful monitoring program includes both pre- and post-injection sampling. It is important to assess the baseline water chemistry and mineralogy in the dilute aquifer of concern, because identification of a CO2 leak and any associated hazard to the aquifer will be made against the baseline measurements. Knowledge of the groundwater flow, permeability, porosity and lithology depth profiles can be used to assess if pre-existing wells can be used for monitoring or if new wells will be needed.
Reactive transport modeling of site geochemistry and hydrology is a highly useful for the design of effective MMV plans for carbon storage. Our simulations of the chemical perturbations associated with a CO2 gas leak into dilute groundwater suggest that more than one monitoring well is needed to detect leaks, because differences between leak flux, CO2 buoyancy, groundwater flow, and aquifer permeability yield asymmetric plumes over time. As a result, leaks have a higher likelihood of being detected if the monitoring well is down gradient from the vertical plume trace and samples the most permeable units. This is seen in Figures 4, 6, 7, 10 and Movies 1–4 (see Additional files 1, 2, 3, 4), where wells within the most permeable units (K = 2.5 × 10-10 m2) and at the base of the aquifer unit for small leaks (CO2 = 103 t/yr, K = 5.4 × 10-11 m2) would miss the leak altogether if the well is up gradient from the leak trace. One exception would be wells that sample groundwater near the top of the aquifer just below the confining layer near the water table (Additional file 1). CO2 spreads laterally along the top of the aquifer, because the confining layer prevents the CO2 from diffusing through the vadose zone to the atmosphere. The extensive transport of the CO2 at the top of the aquifer allows CO2 to be detected far from the leak source irrespective of the direction of groundwater flow. After injection, it is important to sample over time and over a large enough sampling grid to capture pH breakthrough. In our example, the aquifer contains a very permeable unit that allows the CO2 leak to be detected for CO2 flux = 104 t/yr within a 15-month time period. CO2 detection in less permeable aquifers might be achieved over longer sampling interval. These data could then be used in reverse or stochastic simulations to quantify the location, extent, and magnitude of the leak. A large enough sampling grid over time ensures that the MMV plan can capture the CO2 leak and its growth, thus avoiding false positive/negative results from single point measurements. Equally as important, time-series chemical contour maps indicate the aquifer capacity for the CO2 leak and its potential flux to the surface. As an example, the IEA GHG Weyburn carbon dioxide monitoring and storage project injected about 5000 t/d of carbon dioxide into dolomite and limestone oil reservoirs in the southeast corner of Saskatchewan in Western Canada to study carbon dioxide – enhanced oil recovery at this site and to study monitoring, site selection, risk and other issues for CO2 storage . The Weyburn project sampled groundwater chemistry prior to CO2 injection and 11 times over a four-year period after injection from about 35 to 60 wells per 25 square kilometers to create the chemical contour maps showing spatial and temporal trends in carbonate chemistry due to the injection of supercritical CO2 in the reservoir [35, 36]. Data of this kind for an overlying aquifer can be used to inform storage efficiency and future monitoring, remediation, and mitigation programs.
Currently, there are no standards for the containment of stored CO2 in the subsurface. The United States Environmental Protection Agency (US EPA) is currently proposing that owners and operator's demonstrate that geologic storage of CO2 does not endanger US drinking water for a 50 year-time frame prior to closure of the site . The US EPA recommends groundwater geochemistry as a monitoring tool, however assessment of leak magnitude leading to endangerment of drinking waters is still an area of active research [3–8]. One area of concern is the release of toxic metals in acidified water. Our simulations show that CO2 generates a slightly acid solution near pH 5.5. Sorption experiments suggest that a wide range of metals could be desorbed from the iron hydroxides common in sedimentary rocks as the pH is reduced from ambient conditions to pH 5.5 in response to leaking CO2 . It is expected that metals would re-sorb to iron hydroxide phases as the solution is neutralized by reaction or mixing with the ambient groundwater, thus limiting the long-term hazard. The extent of re-sorption will depend on the concentration of other ions in solution. For example, CO2 leaks may be accompanied by higher salinity water found in the storage reservoir. Any metals released at depth or within the drinking water aquifer may remain in the aqueous phase as chloride or organic complexes. In light of the need to protect drinking water, it would be prudent to collect filtered, acidified water samples for additional analysis if required to assess contamination from metals dissolved from hydroxides or other phases present in the sedimentary rocks, as was seen in the CO2 sequestration field demonstration in the Frio Sandstone .
The US EPA regulations on CO2 sequestration do not address minimum standards for leakage on global warming or on ecological or human hazards should anthropogenic CO2 be released to the atmosphere. The aim is to store carbon dioxide in the subsurface for 100s of years. Although a range of geophysical techniques are used to track supercritical CO2 plumes at depth during the injection phase, these techniques are not sensitive enough to confirm effective storage by detecting small changes in the amount stored. It is generally believed that "above zone" monitoring is the best approach to account for the containment of CO2 in the subsurface, because very small releases of stored CO2 will yield large signals. This is clearly the case for CO2 leakage into dilute aquifers. Our simulations show that leakage of ≥ 0.1% (104 t/yr) of the annual amount of stored CO2 from a gigawatt coal fired power plant can be readily detected by changes in pH and carbonate chemistry (Figures 5, 11). Detection of lower fluxes is possible if the monitoring well grid can capture the pH plume at greater depths or if active wells draw the plume toward the well. Although it is possible to detect CO2 using gas samplers at the surface at similar rates, the sampling chambers must be directly over the surface expression of the leak . The ability to detect CO2 leakage at a distance from the leak source is a key advantage over gas sampling at ground surface.
This work was prepared by LLNL under Contract DE-AC52-07NA27344. We thank Andy Tompson and three reviewers for their comments, which significantly improved the quality of this manuscript.
- IEA International Energy Agency: Greenhouse Gas R&D Programme. 2007, [http://www.ieagreen.org.uk/]
- IPCC Intergovernmental Panel on Climate Change: 2007, [http://www.ipcc.ch/]
- Gasda SE, Bachu S, Celia MA: Spatial characterization of the location of potentially leaky wells penetrating a deep saline aquifer in a mature sedimentary basin. Environmental Geology. 2004, 46: 707-720.View Article
- Scherer GW, Celia MA, Provost J-H, Bachu S, Bruant R, Duguid A, Fuller R, Gasda SE, Rodonjic M, Vichit-Vadakan W: Leakage of CO2 through abandoned wells: Role of corrosion of cement. Carbon Dioxide Capture for Storage in Deep Geologic Formations. Edited by: Thomas DC, Benson SM. 2005, 2: 827-848.View Article
- Ide ST, Freidmann SJ, Herzog HJ: CO2 leakage throughexisting wells: Current technology and regulatory basis. Proceedings for the 8th International Conference on Greenhouse Gas Control Technologies: 27–30. 2006, October , Trondheim, Norway
- Hollaway S, Pearce JM, Hards VL, Ohsumi T, Gale J: Natural emissions of CO2 from the geosphere and their bearing on the geological storage of carbon dioxide. Energy. 2007, 32: 1194-1201.View Article
- Lewicki JL, Birkholzer J, Tsang C-F: Natural andindustrial analogues for leakage of CO2 from storage reservoirs: identification of features, events, and processes and lessons learned. Environ Geol. 2007, 52: 457-467.View Article
- Wilson EJ, Friedmann SJ, Pollak MF: Research for deployment: Incorporating risk, regulation, and liability for carbon capture and sequestration. Environ Sci Technol. 2007, 41: 5945-5952.View Article
- Lewicki JL, Oldenburg CM, Dobeck L, Spangler L: SurfaceCO2 leakage during two shallow subsurface CO2 releases. Geophysical Research Letters. 2007, 34: L24402-View Article
- Klausman RW: Evaluation of leakage potential from a carbon dioxide EOR/sequestration project. Energy Conversion and Management. 2003, 44: 1921-1940.View Article
- Klausman RW: A geochemical perspective and assessment of leakage potential for a mature carbon dioxide-enhanced oil recovery project and as a prototype for carbon dioxide sequestration; Rangely field, Colorado. AAPG Bulletin. 2003, 87: 1485-1507.View Article
- Klausman RW: Baseline studies of surface gas exchange and soil-gas composition in preparation for CO2 sequestration research: Teapot Dome, Wyoming. AAPG Bulletin. 2005, 89: 981-1003.View Article
- Beaubien SE, Lombardi S, Ciotoli G, Annunziatellis A, Hatziyannis G, Metaxas A, Pearce JM: Potential hazards of CO2 leakage in storage systems – Learning from natural systems. Proceedings of the 7th International Conference on Greenhouse Gas Control Technologies. 2004, Elsevier Ltd: Vancouver, Canada, 2135-2139.
- Gouveia RJ, Johnson M, Lief RN, Friedmann SJ: Aerometric measurement and modeling of the mass of CO2 emissions from Crystal Geyser, Utah. NETL 4th Annual Carbon Capture and Sequestration Conference: 2–5 May Alexandria VA.
- IEA International Energy Agency: A review of naturalCO2 emissions and releases and their relevance to CO2storage. International Energy Agency Greenhouse Gas Programme. 2005, [http://www.ieagreen.org.uk/]
- IEA International Energy Agency: Natural Emissions of Carbon Dioxide. International Energy Agency Greenhouse Gas Programme. 2006
- Stevens SH, Kuuskraa VA, Gale J: Sequestration of CO2 in Depleted Oil and Gas Fields: Global capacity, costs and barriers. Proceedings of the 5th Annual Greenhouse Gas Technology Conference. 2001, CSIRO Publishing: Cairns, Austrailia
- Bethke CM: Geochemical and Biogeochemical Reaction Modeling. 2008, Cambridge Press
- Nativ R, Smith DA: Hydrogeology and geochemistry of the Ogallala Aquifer, Southern High Plains. J Hydrology. 1987, 91: 217-253.View Article
- McMahon PB, Böhlke JK, Lehman TM: Vertical gradients in water chemistry and age in the southern High Plains Aquifer, Texas, 2002. US Geological Survey, Scientific Investigations Report 2004-5053. 2004
- McMahon PB, Böhlke JK, Christenson SC: Geochemistry, radiocarbon ages, and paleorecharge conditions along a transect in the central High Plains aquifer, southwestern Kansas, USA. Applied Geochemistry. 19: 1655-1686.
- Nitao JJ: Reference Manual for the NUFT Flow and Transport Code, Version 2.0. UCRL-MA-130651. Lawrence Livermore National Laboratory, Livermore, CA. 1998
- Buscheck TA, Glascoe LG, Lee KH, Gansemer J, Sun Y, Mansoor K: Validation of the Multiscale Thermohydrologic Model used for analysis of a proposed repository at Yucca Mountain. J Contam Hydrol. 2003, 62–3: 421-440.View Article
- Glassley WE, Nitao JJ, Grant CW: Three-dimensional spatial variability of chemical properties around a monitored waste emplacement tunnel. J Contaminant Hydrology. 2003, 62–63: 495-507.View Article
- Johnson JW, Nitao JJ, Knauss KG: Reactive transport modeling of CO2 storage in saline aquifers to elucidate fundamental processes, trapping mechanisms and sequestration partitioning. Geological Storage of Carbon Dioxide. Edited by: Baines SJ, Worden RH. 2004, Geological Society, London, Special Publications, 223: 107-128.
- Johnson JW, Nitao JJ, Morris JP: Reactive transport modeling of cap-rock integrity during natural and engineered CO2 storage. Carbon Dioxide Capture for Storage in Deep Geologic Formations. Edited by: Thomas DC, Benson SM. 2005, 2: 787-813.View Article
- Gutentag ED, Heimes FJ, Krothe NC, Luckey RR, Weeks JB: Geohydrology of the High Plains aquifer in parts of Colorado, Kansas, Nebraska, New Mexico, Oklahoma, South Dakota, Texas, and Wyoming. US Geological Survey Professional Paper 1400-B. 1984
- Lucky RR, Gutentag ED, Heimes FJ, Weeks JB: Digital simulation of ground-water flow in the High Plains Aquifer in parts of Colorado, Kansas, Nebraska, New Mexico, Oklahoma, South Dakota, Texas, and Wyoming. US Geological Survey Professional Paper 1400-D. 1986
- Freeze RA, Cherry JA: Groundwater. 1984, Prentice-Hall Inc
- Oldenburg CM, Unger AJA: On leakage and seepage from geologic carbon sequestration sites: Unsaturated zone attenuation. Vadose Zone J. 2003, 2: 287-296.
- Altevogt AS, Celia MA: Numerical modeling of carbon dioxide in unsaturated soils due to deep subsurface leakage. Water Resources Research. 2004, 40: W03509-View Article
- Freifeld BM, Trautz RC: Real-time quadrupole mass spectrometer analysis of gas in borehole fluid samples acquired using the U-tube sampling methodology. Geofluids. 2006, 6: 217-224.
- Freifeld BM, Trautz RC, Kharaka YK, Phelps TJ, Myer LR, Hovorka SD, Collins DJ: The U-tube: A novel system for acquiring borehole fluid samples from a deep geologic CO2 sequestration experiment. J Geophysical Research-Solid Earth. 2005, 110: B10203-View Article
- Preston C, Monea M, Jazrawi W, Brown K, Whittaker S, White D, Law D, Chalaturnayk R, Rostron B: IEA GHG Weyburn CO2 monitoring and storage project. Fuel Processing Technology. 2005, 86: 1547-1568.View Article
- Shevalier M, Durocher K, Perez R, Hutcheon I, Mayer B, Perkens E, Gunter W: Geochemical monitoring of gas-water-rock interaction at the IEA Weyburn CO2 Monitoring and Storage Project, Saskatchewan, Canada. Proceedings of the 7th International Conference on Greenhouse Gas Control Technologies. 2005, Elsevier Ltd: Vancouver, Canada, 2135-2139.
- Hirsche K, Davis T, Hutcheon I, Adair R, Burrowes G, Graham S, Bencini R, Majer E, Maxwell SC: Prediction, Monitoring and Verification of CO2 Movements. IEA GHG Weyburn CO2 Monitoring and Storage Project Summary Report 2000–7th International Conference on Greenhouse Gas Control Technologies: 5–9 September 2004, Vancouver, Canada. Edited by: Wilson M, Monea M. 2004
- U S Environmental Protection Agency: Federal Requirements Under the Underground Injection Control (UIC) Program for Carbon Dioxide (CO2) Geologic Sequestration (GS) Wells. Federal Registrar. 2008, 73: 43492-43541.
- Dzombak DA, Morel FMM: Surface Complexation Modeling: Hydrous Ferric Oxide. 1990, A Wiley-Interscience Publication
- Kharaka YK, Cole DR, Hovorka SD, Gunter WD, Knauss KG, Freifeld B: Gas-water-rock interactions in Frio Formation following CO2 injection: Implications for the storage of greenhouse gases in sedimentary basins. Geology. 2006, 34: 577-580.View Article
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